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1) "Photochemical" -- As to photochemical pho·to·chem·i·cal Pronunciation: "fO-tO-'ke-mi-k&l Function: adjective 1 : of, relating to, or resulting from the chemical action of radiant energy and especially light <photochemical smog> 2 : of or relating to photochemistry <photochemical studies> - pho·to·chem·i·cal·ly /-k(&-)lE/ adverb Pronunciation Symbols Illustration of the electromagnetic spectrum. Note the visible spectrum, as well as ultraviolet and infrared regions. Photochemistry, a sub-discipline of chemistry, is the study of the interactions between atoms, small molecules, and light (or electromagnetic radiation). Like most scientific disciplines, photochemistry utilizes the SI or metric measurement system. Important units and constants that show up regularly include meters (and variants such as centimeter, millimeter, micrometer, nanometer, etc.), seconds, hertz, joules, moles, the gas constant R, and the Boltzmann constant. These units and constants are also integral to the field of physical chemistry. The first law of photochemistry, known as the Grotthuss-Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place. The second law of photochemistry, the Stark-Einstein law, states that for each photon of light absorbed by a chemical system, only one molecule is activated for a photochemical reaction. This is also known as the photoequivalence law and was derived by Albert Einstein at the time when the quantum (photon) theory of light was being developed. Photochemistry may also be introduced to laymen as a reaction that proceeds with the absorption of light. Normally a reaction (not just a photochemical reaction) occurs when a molecule gains necessary energy activation energy to undergo change. A simple example can be the combustion of gasoline (a hydrocarbon) into carbon dioxide and water. This is a chemical reaction where one or more molecules/chemical species are converted into others. For this reaction to take place activation energy should be supplied. The activation energy is provided in the form of heat or a spark. In case of photochemical reactions light provides the activation energy. The absorption of a photon of light by a reactant molecule may also permit a reaction to occur not just by bringing the molecule to the necessary activation energy, but also by changing the symmetry of the molecule's electronic c..."
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